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Milka's grandmother planted 12 rows of vegetables. 1/6 of the rows are carrots. The rest is parsley. How many rows are planted with parsley? To a solution of [59557-90-3]4-bromo-3,5-dimethylaniline (3.47 g, 17.4 mmol) and diisopropylethylamine (5.3 mL, 30.4 mmol) in DMI (13 mL), 2-bromoisobutyric acid (3.86 g, 23.1 mmol) was added at room temperature. The mixture was stirred at 100C for one hour. And then 2-bromoisobutyrate (496 mg, 2.97 mmol) and diisopropylethylamine (0.8 mL, 4.59 mmol) was added and the mixture was stirred at 100C for one hour. Methanol (52 mL) and a 5 N aqueous sodium hydroxide solution (52 mL, 260 mmol) were added to the reaction mixture at room temperature, and then this mixture was stirred at 75C for 1.5 hours. The reaction mixture was cooled, followed by addition of water and adjustment of the pH to 5 using a 1 N aqueous potassium hydrogen sulfate solution, and then extracted using ethyl acetate. The organic layer was washed with water, then dried over anhydrous magnesium sulfate, and concentrated to yield 2-((4-bromo-3,5-dimethylphenyl)amino)-2-methyl propanoic acid as a crude product (5.79 g). MS(ESI) m/z = 286,288 (M+H)+ Step) 4'-amino-2',6'-dimethyl-[1,1'-biphenyl] -3-carboxylate[59557-90-3]4-bromo-3,5-dimethylaniline (lg, lOmmol), (3- (methoxycarbonyl) phenyl) borate (2 · 7g, 15mmol), potassium carbonate (4 · 14g, 30mmol), [ 1,1 '- bis (diphenylphosphino) ferrocene] dichloropalladium dichloromethane complex (. 0. 37g, 0 5mmol) was dissolved in N, N-dimethylformamide (30mL) and water (10mL), and stirred at 90 C for 1 hour. The reaction was cooled to room temperature and added water (30 mL) was diluted with ethyl acetate (200mL X 2), the combined organic phase was washed with saturated sodium chloride solution (50 mL), dried over anhydrous sodium sulfate, filtered, and the filtrate was concentrated under reduced pressure. The residue was purified by silica gel column chromatography (petroleum ether: ethyl acetate = 4: 1) to give the title compound as a pale yellow solid (2. 1g, 82% yield). With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate; In N,N-dimethyl-formamide; at 90℃; for 1h; Silica gel was added to the reaction mixture and the solvent was evaporated under reduced pressure.

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To a mixture of cyclopentanone (42 mg, 0.500 mmol) and [59557-90-3]4-bromo-3,5-dimethylaniline (100 mg, 0.500 mmol) in acetic acid (0.5 mL), trimethylsilyl cyanide (0.063 ml, 0.500 mmol) was added at room temperature. The mixture was stirred at room temperature for 1.5 hours under nitrogen atmosphere. The reaction mixture was quenched with 28% aqueous ammonia (1 mL), diluted with water and extracted with dichloromethane. The organic layer was washed with water and brine, dried over anhydrous sodium sulfate, and then concentrated under reduced pressure to afford 1-((4-bromo-3,5-dimethylphenyl)amino)cyclopentanecarbonitrile as a crude product (152 mg). 1H-NMR (400MHz, CDCl3) delta: 1.83-1.92 (4H, m), 2.07-2.15 (2H, m), 2.33-2.42 (2H, m), 2.37 (6H, m), 3.71 (1H, brs), 6.56 (2H, s)

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To a solution of 3,5-dimethylaniline 1a (80 g, 660 mmol) in 800 mL MeCN was added a solution of NBS (117g, 660mmol) in 400 ml MeCN at ice-bath, stirred at room temperature for 16h. The reaction mixture was concentratedunder reduced pressure. The residue was purified by silica column chromatography (Eluent C) to give title product 4-bromo-3,5-dimethylaniline 1b (90 g, yellow solid), yield: 68.2%.MS m/z (ESI): 200 [M+1]

Fraction calculator - calculation: 3/4 - HackMath

If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If you look at the mixed fraction 30 0/3, you'll see that the numerator is the same as the remainder (0), the denominator is our original divisor (3), and the whole number is our final answer (30). With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate; In water; N,N-dimethyl-formamide; at 90℃; for 1h; What is 90 Divided by 3 Using Long Division?". VisualFractions.com. Accessed on November 2, 2023. http://visualfractions.com/calculator/long-division/what-is-90-divided-by-3-using-long-division/. In a letter puzzle game, John can use every alphabet only once. He used only 8 alphabets to solve the puzzle. What fraction of the 26 alphabets did he use? Express your answer as a fraction in the simplest form.Jurgen Klopp's side looked to be strolling to victory after dominating the opening phase and scoring three goals, only to then deliver a sloppy, careless and complacent performance to throw Spurs several lifelines.

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Liverpool's rearguard was exposed at regular intervals and they were thankful for the woodwork twice in the second half as Spurs, who looked out of contention, gratefully accepted the encouragement they were being given.To a solution of 3,5-dimethylaniline 1a (80 g, 660 mmol) in 800 mL MeCN was added a solution of NBS (117g, 660mmol) in 400 ml MeCN at ice-bath, stirred at room temperature for 16h. The reaction mixture was concentratedunder reduced pressure. The residue was purified by silica column chromatography (Eluent C) to give title product 4-bromo-3,5-dimethylaniline 1b (90 g, yellow solid), yield: 68.2percent.MS m/z (ESI): 200 [M+1] Sloppy Liverpool escape to victory Mohamed Salah's goal was his 184th for Liverpool in 300 appearances Tottenham's season has been characterised by slow starts and they paid the price once more for failing to get to grips with the game in the opening phase. The worst example was in that 6-1 debacle on Tyneside a week ago, and they looked on course for a repeat here as Liverpool took advantage of Spurs sleepwalking once again to race into that early lead.

4-3 Tottenham Hotspur: Reds edge Spurs in seven Liverpool 4-3 Tottenham Hotspur: Reds edge Spurs in seven

Spurs actually had chances to give Liverpool even more anxious moments but both Son Heung-min and Cristian Romero hit the post within seconds in the second half.Flow control valves, centering bushings, O-rings for direct connection, fitting screws (SRU-plus 63 only), assembly and operating manual with manufacturer’s declaration Liverpool move up to fifth to retain slim hopes of Champions League football but earlier victories for Manchester United and Newcastle United make this an increasingly long shot.